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              <p>Decreasing oil supplies and increasing energy demand provide incentives to find          alternative fuels. First, the valorisation of edible crops for ethanol and biodiesel          production led to first generation biofuels. Nowadays, research is focused on          lignocellulosic biomass as a source of renewable carbon (second generation biofuels).          Whereas the cellulosic ethanol production is in progress, a new way consisting of the          transformation of ex-lignocellulose sugars and polyols towards light hydrocarbons by          heterogeneous catalysis in aqueous phase has been recently described.This process is performed under mild conditions (T &lt; 300 °C and P &lt; 50 bar). It          requires on one hand hydrogen formation by catalytic reforming of carbohydrates in aqueous          phase and on the other hand, the dehydration/hydrogenation of polyols leading to alkanes          by selective C-O bond cleavages. The challenge here is to conceive multifunctional          catalytic systems that are stable, active and selective under the reaction conditions.The aim of this article is to present the involved reactions, the catalytic systems          described in literature for that kind of transformation and examples of industrial          applications.</p>
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