Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to cross the Si / Al lower limit
Résumé
A family of Al-rich ZSM-5 zeolites with Si / Al = 8 ± 0.5 was prepared according to a biomass-mediated supramolecular approach. A combination of advanced characterisation techniques and periodic density functional theory (DFT) calculations unraveled the purity and stability of unexpected Al-enriched ZSM-5 structures, hence allowing to cross the frontier of Si / Al lower limit. In addition, these Al-rich ZSM-5 zeolites demonstrated high catalytic activity in n-hexane cracking and methanol conversion into hydrocarbons, being in line with the presence of numerous BrØnsted acid sites.
Domaines
Chimie
Fichier principal
Louis_Chem Science-post-print.pdf (910.54 Ko)
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Biomass suplementary.pdf (2.02 Mo)
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| Origine | Fichiers produits par l'(les) auteur(s) |
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